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This may be contrasted with the following picture which shows a schematic of a reconstructed surface - this particular example is similar to the "missing row model" proposed for the structure of a number of reconstructed (110) fcc metal surfaces.

Since reconstruction involves a change in the periodicity of the surface and in some cases also a change in surface symmetry, it is readily detected using surface diffraction techniques (e.g. LEED RHEED ).

The overall driving force for reconstruction is once again the minimization of the surface free energy - at the atomic level, however, it is not always clear why the reconstruction should reduce the surface free energy. For some metallic surfaces, it may be that the change in periodicity of the surface induces a splitting in surface-localized bands of energy levels and that this can lead to a lowering of the total electronic energy when the band is initially only partly full.

In the case of many semiconductors, the simple reconstructions can often be explained in terms of a "surface healing" process in which the co-ordinative unsaturation of the surface atoms is reduced by bond formation between adjacent atoms. For example, the formation of a Si(100) surface requires that the bonds between the Si atoms that form the new surface layer and those that were in the layer immediately above in the solid are broken - this leaves two "dangling bonds" per surface Si atom.

A relatively small co-ordinated movement of the atoms in the topmost layer can reduce this unsatisfied co-ordination - pairs of Si atoms come together to form surface "Si dimers", leaving only one dangling bond per Si atom. This process leads to a change in the surface periodicity : the period of the surface structure is doubled in one direction giving rise to the so-called (2x1) reconstruction observed on all clean Si(100) surfaces [ nike air force 1 all white cheap dresses
].

In this section, attention has been concentrated on the reconstruction of clean surfaces. It is, however, worth noting that reconstruction of the substrate surface is frequently induced by the adsorption of molecular or atomic species onto the surface - this phenomenon is known as adsorbate-induced reconstruction (see Section 2.5 for some examples).

Summary

The minimisation of surface energy means that even single crystal surfaces will not exhibit the ideal geometry of atoms to be expected by truncating the bulk structure of the solid parallel to a particular plane. The differences between the real structure of the clean surface and the ideal structure may be imperceptibly small (e.g. a very slight surface relaxation ) or much more marked and involving a change in the surface periodicity in one or more of the main symmetry directions ( surface reconstruction ).

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